Chemodex

(1R)-(-)-Nopol

Product Code:
 
CDX-N0658
Product Group:
 
Other Biochemicals
Supplier:
 
Chemodex
Regulatory Status:
 
RUO
Shipping:
 
Ambient
Storage:
 
Short term: +20°C. Long term: +20°C
Chemical Structure

Chemical Structure 

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CodeSizePrice
CDX-N0658-G05050 g£65.00
Quantity:
CDX-N0658-G100100 g£95.00
Quantity:
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This product comes from: Switzerland.
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  • Further Information
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Further Information

Appearance:
Colourless viscous liquid.
CAS:
35836-73-8
Description:
(1R)-Nopol is a chiral terpenol derivative, that can be used as a building block and intermediate for synthesis. Has been used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids. Reacts with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization. Can be used as a starting material for Pinaverium bromide, a selective gastrointestinal calcium ion antagonist used to treat irritable bowel syndrome. Due to its woody and minty aroma, Nopol is often used as a starting material for flavorings and fragrances. Gives a clean note for soaps and detergents.
EClass:
32160000
Form:
liquid
GHS:
GHS07
Handling Advice:
Protect from light and moisture.
Hazards:
H302-H315-H319-H335
InChi:
InChI=1S/C11H18O/c1-11(2)9-4-3-8(5-6-12)10(11)7-9/h3,9-10,12H,4-7H2,1-2H3/t9-,10-/m0/s1
InChi Key:
ROKSAUSPJGWCSM-UWVGGRQHSA-N
MDL:
MFCD00075187
Molecular Formula:
C11H18O
Molecular Weight:
166.26
Package Type:
Vial
Precautions:
P261-P264-P271-P301 + P312-P302 + P352-P305 + P351 + P338
Purity:
>98% (GC)
Signal word:
Warning
SMILES:
OCCC1=CC[C@]2([H])C(C)(C)[C@@]1([H])C2
Solubility:
Slightly soluble in chloroform or MeOH.
Source / Host:
Synthetic
Transportation:
Non-hazardous
UNSPSC Number:
12352200
Use & Stability:
Stable for at least 2 years after receipt when stored at RT.

Documents

References

(1) D.R. Arnold & X. Du; Can. J. Chem. 72, 403 (1994) | (2) M. Miyazawa, et al.; Phytochem. 39, 337 (1995) | (3) J.V. Crivello & S.S. Liu; J. Polymer Sci. Part A Polymer Chem. 37, 1199 (1999) | (4) L. Cointeaux, et al.; Tetrahedr. Lett. 43, 6275 (2002) | (5) E. Barriau, et al.; Macromolecules 41, 3779 (2008) | (6) R.A. Cherkasov, et al.; Phosph. Sulfur Relat. Elem. 186, 1003 (2011)